(DOWNLOAD) "Studies on Green Synthetic Reactions Based on Formic Acid from Biomass" by Ming-Chen Fu " Book PDF Kindle ePub Free
eBook details
- Title: Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
- Author : Ming-Chen Fu
- Release Date : January 10, 2020
- Genre: Chemistry,Books,Science & Nature,
- Pages : * pages
- Size : 12597 KB
Description
This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized Îą, Îē- and Îē, Îģ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry.
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